Eject key on Logitech K750 doesn't work

Welcome to the forum, @Sebastien.

Straightforward answer: those keys are for internal use, so forget about them and use other key combinations instead.

@Airy is correct about the fn key and indeed this subject is covered in the FAQ:

The Fn key is not a modifier, it is a hardware toggle that toggles whether the physical key behaves as a function key (eg F3) or a hardware key (eg increase brightness).

That said, some people have reported that success using other software, including BetterTouchTool, and then using that to trigger Keyboard Maestro. In order for that to work, the keyboard in question would need to be sending some kind of signal when fn were pressed (it would certainly not be one that is supported by Apple’s public APIs, and the policy with KM is to use only those).

Excerpts from an old thread:

And surprisingly, @Airy, you said there that you had had some success too?! :exploding_head:

So anyway, no, Keyboard Maestro cannot directly support fn or esc... so choose other hot keys.