Thanks for the pointer about Applescript.
Had to refresh Applescript notes from the days of Applescript studio to modify and do it in 1 step.
tell application "Finder"
open (sort every file of the ¬
desktop by creation date)'s last item
end tell
Figured the shell script to get it working.
#!/usr/bin/env bash
cd ~/Desktop
/usr/local/bin/rename -v 's/Screen Shot (\d{4}-\d{2}-\d{2}) at (\d{1,2}\.\d{2}\.\d{2}) ([AP]M)\.png/SShot_$1_$2_$3\.png/' *.png
SCRSHOT=$(ls|grep png| sort -r | head -1)
open -a /Applications/Preview.app ./$SCRSHOT